Matches in SemOpenAlex for { <https://semopenalex.org/work/W2514514068> ?p ?o ?g. }
Showing items 1 to 100 of
100
with 100 items per page.
- W2514514068 endingPage "6034" @default.
- W2514514068 startingPage "6016" @default.
- W2514514068 abstract "Using particle-based simulation of a soft, coarse-grained model and self-consistent field theory (SCFT), we investigate the properties of dense living polymer systems with ring formation both in the bulk and in thin films. In the bulk, our results confirm that the molecular weight distribution of ring polymers exhibits a combination of an exponential decay and a power law. The exponential molecular weight distribution of linear chains is hardly affected by ring formation, only the corresponding mean molecular weight is slightly reduced. At lower segment density, the fraction of monomers of ring polymers is increased. In thin films, ring formation does not influence the width of the narrow interface, where the segment density rises to the bulk value. Since the molecular extension of ring polymers is smaller than that of linear chains, the spatial extent of the wide interphase is, however, reduced. In the narrow interface, we find that the local ring formation is affected by five aspects: (1) the mirroring of chain conformations and back-folding by the solid substrate (Silberberg argument) and other four aspects at the solid substrate, i.e., (2) the reduced segment density, (3) the enrichment of chain ends, (4) the pronounced segregation of nonbonded monomers, and (5) the reduced dimensionality of ring polymers. In the wide interphase, the local ring formation is enhanced mainly by the first aspect. By comparing the results from the particle-based simulation and SCFT, we observe good agreement in the wide interphase, but the difference in the local structure leads to differences in the narrow interface. Additionally, the SCFT results show that a decrease of the film thickness increases the global ring formation within the thin film." @default.
- W2514514068 created "2016-09-16" @default.
- W2514514068 creator A5012585792 @default.
- W2514514068 creator A5032918016 @default.
- W2514514068 date "2015-08-05" @default.
- W2514514068 modified "2023-10-12" @default.
- W2514514068 title "Living Polymer Systems at a Solid Substrate: Computer Simulation of a Soft, Coarse-Grained Model and Self-Consistent Field Theory" @default.
- W2514514068 cites W1964129069 @default.
- W2514514068 cites W1971790040 @default.
- W2514514068 cites W1972069027 @default.
- W2514514068 cites W1983070457 @default.
- W2514514068 cites W1988749234 @default.
- W2514514068 cites W2001226508 @default.
- W2514514068 cites W2023119977 @default.
- W2514514068 cites W2035013710 @default.
- W2514514068 cites W2041862937 @default.
- W2514514068 cites W2052276906 @default.
- W2514514068 cites W2057291289 @default.
- W2514514068 cites W2058840896 @default.
- W2514514068 cites W2064888668 @default.
- W2514514068 cites W2072437464 @default.
- W2514514068 cites W2073262179 @default.
- W2514514068 cites W2080247153 @default.
- W2514514068 cites W2086272714 @default.
- W2514514068 cites W2094083279 @default.
- W2514514068 cites W2094709211 @default.
- W2514514068 cites W2113404900 @default.
- W2514514068 cites W2123373748 @default.
- W2514514068 cites W2133427811 @default.
- W2514514068 cites W2168666533 @default.
- W2514514068 cites W2325836316 @default.
- W2514514068 cites W2334350380 @default.
- W2514514068 cites W3103918666 @default.
- W2514514068 cites W3105540400 @default.
- W2514514068 cites W314031892 @default.
- W2514514068 doi "https://doi.org/10.1021/acs.macromol.5b01055" @default.
- W2514514068 hasPublicationYear "2015" @default.
- W2514514068 type Work @default.
- W2514514068 sameAs 2514514068 @default.
- W2514514068 citedByCount "1" @default.
- W2514514068 countsByYear W25145140682020 @default.
- W2514514068 crossrefType "journal-article" @default.
- W2514514068 hasAuthorship W2514514068A5012585792 @default.
- W2514514068 hasAuthorship W2514514068A5032918016 @default.
- W2514514068 hasConcept C111368507 @default.
- W2514514068 hasConcept C127313418 @default.
- W2514514068 hasConcept C147597530 @default.
- W2514514068 hasConcept C159467904 @default.
- W2514514068 hasConcept C159985019 @default.
- W2514514068 hasConcept C166940927 @default.
- W2514514068 hasConcept C178790620 @default.
- W2514514068 hasConcept C185592680 @default.
- W2514514068 hasConcept C192562407 @default.
- W2514514068 hasConcept C2777289219 @default.
- W2514514068 hasConcept C2780378348 @default.
- W2514514068 hasConcept C29452124 @default.
- W2514514068 hasConcept C521977710 @default.
- W2514514068 hasConcept C54355233 @default.
- W2514514068 hasConcept C59593255 @default.
- W2514514068 hasConcept C8010536 @default.
- W2514514068 hasConcept C86803240 @default.
- W2514514068 hasConceptScore W2514514068C111368507 @default.
- W2514514068 hasConceptScore W2514514068C127313418 @default.
- W2514514068 hasConceptScore W2514514068C147597530 @default.
- W2514514068 hasConceptScore W2514514068C159467904 @default.
- W2514514068 hasConceptScore W2514514068C159985019 @default.
- W2514514068 hasConceptScore W2514514068C166940927 @default.
- W2514514068 hasConceptScore W2514514068C178790620 @default.
- W2514514068 hasConceptScore W2514514068C185592680 @default.
- W2514514068 hasConceptScore W2514514068C192562407 @default.
- W2514514068 hasConceptScore W2514514068C2777289219 @default.
- W2514514068 hasConceptScore W2514514068C2780378348 @default.
- W2514514068 hasConceptScore W2514514068C29452124 @default.
- W2514514068 hasConceptScore W2514514068C521977710 @default.
- W2514514068 hasConceptScore W2514514068C54355233 @default.
- W2514514068 hasConceptScore W2514514068C59593255 @default.
- W2514514068 hasConceptScore W2514514068C8010536 @default.
- W2514514068 hasConceptScore W2514514068C86803240 @default.
- W2514514068 hasFunder F4320320879 @default.
- W2514514068 hasIssue "16" @default.
- W2514514068 hasLocation W25145140681 @default.
- W2514514068 hasOpenAccess W2514514068 @default.
- W2514514068 hasPrimaryLocation W25145140681 @default.
- W2514514068 hasRelatedWork W1779230222 @default.
- W2514514068 hasRelatedWork W1979272585 @default.
- W2514514068 hasRelatedWork W1995946584 @default.
- W2514514068 hasRelatedWork W2003526228 @default.
- W2514514068 hasRelatedWork W2083754170 @default.
- W2514514068 hasRelatedWork W2287480013 @default.
- W2514514068 hasRelatedWork W2753346919 @default.
- W2514514068 hasRelatedWork W2760368345 @default.
- W2514514068 hasRelatedWork W3089212823 @default.
- W2514514068 hasRelatedWork W3095489617 @default.
- W2514514068 hasVolume "48" @default.
- W2514514068 isParatext "false" @default.
- W2514514068 isRetracted "false" @default.
- W2514514068 magId "2514514068" @default.
- W2514514068 workType "article" @default.