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• W2514644246 startingPage "7212" @default.
• W2514644246 abstract "The CO2 solubility in N-ethylmonoethanolamine (EMEA) solutions was investigated using the vapor–liquid equilibrium (VLE) and the absorption–desorption apparatus. A tertiary amine, N,N-diethylethanolamine (DEEA), was used as a novel solvent, and other nonaqueous solvents, diethylene glycol, triethylene glycol, benzyl alcohol, n-butyl alcohol and polyethylene glycol-200, were used for comparison. The EMEA + DEEA solution displayed a much higher CO2 solubility than other nonaqueous solutions though lower than the EMEA + H2O solution in the VLE experiment. However, the EMEA + DEEA solution exhibited a higher cyclic absorption capacity than EMEA + H2O solution in the cyclic absorption–desorption experiment. The reaction mechanism of EMEA + DEEA + CO2 was investigated by 13C NMR spectroscopy, which indicated that the nonaqueous solvent of DEEA participated in the chemical absorption of CO2, and thus improved the CO2 solubility. The tertiary amine DEEA used as a nonaqueous solvent shows more excellent performance than alcohols and glycols." @default.
• W2514644246 created "2016-09-16" @default.
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• W2514644246 date "2015-07-14" @default.
• W2514644246 modified "2023-09-24" @default.
• W2514644246 title "Solubility and Characterization of CO₂ in 40 mass % <i>N</i>-Ethylmonoethanolamine Solutions: Explorations for an Efficient Nonaqueous Solution" @default.
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• W2514644246 doi "https://doi.org/10.1021/acs.iecr.5b01654" @default.
• W2514644246 hasPublicationYear "2015" @default.
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