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• W2514658730 endingPage "1395" @default.
• W2514658730 startingPage "1390" @default.
• W2514658730 abstract "The Yb III atom in the title complex, [Yb(C 27 H 24 Cl 3 N 4 O 3 )] [systematic name: (2,2′,2′′-{(nitrilo)tris[ethane-2,1-diyl(nitrilo)methylylidene]}tris(4-chlorophenolato)ytterbium(III)], is coordinated by a trinegative, heptadentate ligand and exists within an N 4 O 3 donor set, which defines a capped octahedral geometry whereby the amine N atom caps the triangular face defined by the three imine N atoms. The packing features supramolecular layers that stack along the a axis, sustained by a combination of aryl-C—H...O, imine-C—H...O, methylene-C—H...π(aryl) and end-on C—Cl...π(aryl) interactions. A Hirshfeld surface analysis points to the major contributions of C...H/ H...C and Cl...H/H...Cl interactions (along with H...H) to the overall surface but the Cl...H contacts are at distances greater than the sum of their van der Waals radii." @default.
• W2514658730 created "2016-09-16" @default.
• W2514658730 creator A5019105081 @default.
• W2514658730 creator A5066327330 @default.
• W2514658730 creator A5082501383 @default.
• W2514658730 date "2016-09-05" @default.
• W2514658730 modified "2023-10-16" @default.
• W2514658730 title "(Tris{2-[(5-chloro-2-oxidobenzylidene-κ<i>O</i>)amino-κ<i>N</i>]ethyl}amine-κ<i>N</i>)ytterbium(III): crystal structure and Hirshfeld surface analysis" @default.
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• W2514658730 doi "https://doi.org/10.1107/s2056989016013748" @default.
• W2514658730 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/5050761" @default.
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• W2514658730 hasPublicationYear "2016" @default.
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