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• W2514693661 abstract "A highly enantioselective synthesis of (R)- and (S)-α-trifluoromethyl (CF3) propanoic acids has been achieved via asymmetric hydrogenation of 2-trifluoromethylacrylic acid using RuBINAP-Cl2 catalyst followed by salt resolution with threoninol. Both enantiomers can be obtained as threoninol salts in good yield and with high enantiomeric excess. Amide coupling conditions that minimize racemization of the chiral acid have also been developed." @default.
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• W2514693661 date "2016-10-01" @default.
• W2514693661 modified "2023-09-26" @default.
• W2514693661 title "Synthesis of ( R )- and ( S )-α-trifluoromethyl propanoic acids via asymmetric hydrogenation followed by salt resolution" @default.
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• W2514693661 doi "https://doi.org/10.1016/j.tetasy.2016.07.004" @default.
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