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- W2514804966 abstract "Abstract The nature of intermolecular interactions occurring between ionic liquid, 1-butyl-3-methylimidazolium bromide, [Bmim]Br and monosaccharides viz. d (−)-ribose and d (−)-arabinose have been studied by measuring the speed of sound of [Bmim]Br in water and in (0.10, 0.20, 0.30, and 0.40) mol·kg − 1 aqueous monosaccharides solutions at temperatures (288.15 to 318.15) K and at 101.3 kPa. Infinite dilution partial molar isentropic compression, K s,2 ° and the empirical parameters ( S K and B k ) have been calculated from apparent molar isentropic compression, K s,2,ϕ , by using Redlich-Mayer type of equation. The isentropic compression of transfer, ∆ t K s,2 ° have also been calculated and was found to be positive, which increase with increase in concentration of monosaccharide and temperature. Positive ∆ t K s,2 ° values observed suggest the dominance of hydrophilic-ionic interactions between ions of [Bmim]Br and monosaccharides. Effect of stereochemistry of monosaccharides on the solvation behavior of [Bmim]Br has also been discussed." @default.
- W2514804966 created "2016-09-16" @default.
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- W2514804966 date "2016-11-01" @default.
- W2514804966 modified "2023-09-26" @default.
- W2514804966 title "Speed of sound and apparent molar isentropic compression of 1-butyl-3-methylimidazolium bromide in aqueous monosaccharide solutions" @default.
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- W2514804966 doi "https://doi.org/10.1016/j.molliq.2016.08.022" @default.
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