FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2515062708> ?p ?o ?g. }

• W2515062708 endingPage "23977" @default.
• W2515062708 startingPage "23973" @default.
• W2515062708 abstract "The H–D exchange reaction is one of the easiest ways to synthesize deuterium-labeled compounds. H–D exchange of olefins has been widely studied on metal surfaces such as Pd and Pt. However, H–D exchange of butene on these surfaces is hardly completed and always accompanied by hydrogenation or dehydrogenation, and its reaction mechanism is yet to be elucidated. In the present study, we investigated the reaction of cis-2- and 1-butenes with H and D atoms absorbed in the near-surface region of Pd70Au30(110) by using thermal desorption spectroscopy (TDS), reflection–absorption infrared spectroscopy (RAIRS), and TDS simulation. We show complete H–D exchange of both butene isomers without hydrogenation and dehydrogenation. Similar product yield distributions for both butene isomers indicate a fast di-σ bond migration on this surface, which is a key for the complete H–D exchange. Our results would lead to understanding and controlling the catalytic activity and selectivity of the Pd–Au alloy and Pd-related surfaces and would open up a new chemistry using absorbed hydrogen in combination with alloyed surfaces." @default.
• W2515062708 created "2016-09-16" @default.
• W2515062708 creator A5036715462 @default.
• W2515062708 creator A5084760447 @default.
• W2515062708 creator A5090975717 @default.
• W2515062708 date "2015-10-12" @default.
• W2515062708 modified "2023-10-01" @default.
• W2515062708 title "Complete H–D Exchange of Butene via D Absorbed in a Pd–Au Alloy" @default.
• W2515062708 cites W1967072952 @default.
• W2515062708 cites W1971732150 @default.
• W2515062708 cites W1997282638 @default.
• W2515062708 cites W2004546166 @default.
• W2515062708 cites W2018523021 @default.
• W2515062708 cites W2025201093 @default.
• W2515062708 cites W2034522900 @default.
• W2515062708 cites W2044926013 @default.
• W2515062708 cites W2067232632 @default.
• W2515062708 cites W2070161253 @default.
• W2515062708 cites W2080509109 @default.
• W2515062708 cites W2080804906 @default.
• W2515062708 cites W2100657568 @default.
• W2515062708 cites W2117636074 @default.
• W2515062708 cites W2122847007 @default.
• W2515062708 cites W2123277227 @default.
• W2515062708 cites W2141250603 @default.
• W2515062708 cites W2146020529 @default.
• W2515062708 cites W2150925176 @default.
• W2515062708 cites W2151523900 @default.
• W2515062708 cites W2313661101 @default.
• W2515062708 cites W2334715082 @default.
• W2515062708 cites W2949962129 @default.
• W2515062708 doi "https://doi.org/10.1021/acs.jpcc.5b07216" @default.
• W2515062708 hasPublicationYear "2015" @default.
• W2515062708 type Work @default.
• W2515062708 sameAs 2515062708 @default.
• W2515062708 citedByCount "9" @default.
• W2515062708 countsByYear W25150627082016 @default.
• W2515062708 countsByYear W25150627082017 @default.
• W2515062708 countsByYear W25150627082018 @default.
• W2515062708 countsByYear W25150627082020 @default.
• W2515062708 crossrefType "journal-article" @default.
• W2515062708 hasAuthorship W2515062708A5036715462 @default.
• W2515062708 hasAuthorship W2515062708A5084760447 @default.
• W2515062708 hasAuthorship W2515062708A5090975717 @default.
• W2515062708 hasConcept C118792377 @default.
• W2515062708 hasConcept C119889771 @default.
• W2515062708 hasConcept C121332964 @default.
• W2515062708 hasConcept C134121241 @default.
• W2515062708 hasConcept C147789679 @default.
• W2515062708 hasConcept C153642686 @default.
• W2515062708 hasConcept C161790260 @default.
• W2515062708 hasConcept C178790620 @default.
• W2515062708 hasConcept C185592680 @default.
• W2515062708 hasConcept C191897082 @default.
• W2515062708 hasConcept C192562407 @default.
• W2515062708 hasConcept C2776164856 @default.
• W2515062708 hasConcept C2778597550 @default.
• W2515062708 hasConcept C2780026712 @default.
• W2515062708 hasConcept C32891209 @default.
• W2515062708 hasConcept C512968161 @default.
• W2515062708 hasConcept C544153396 @default.
• W2515062708 hasConcept C58364064 @default.
• W2515062708 hasConcept C62520636 @default.
• W2515062708 hasConcept C75473681 @default.
• W2515062708 hasConceptScore W2515062708C118792377 @default.
• W2515062708 hasConceptScore W2515062708C119889771 @default.
• W2515062708 hasConceptScore W2515062708C121332964 @default.
• W2515062708 hasConceptScore W2515062708C134121241 @default.
• W2515062708 hasConceptScore W2515062708C147789679 @default.
• W2515062708 hasConceptScore W2515062708C153642686 @default.
• W2515062708 hasConceptScore W2515062708C161790260 @default.
• W2515062708 hasConceptScore W2515062708C178790620 @default.
• W2515062708 hasConceptScore W2515062708C185592680 @default.
• W2515062708 hasConceptScore W2515062708C191897082 @default.
• W2515062708 hasConceptScore W2515062708C192562407 @default.
• W2515062708 hasConceptScore W2515062708C2776164856 @default.
• W2515062708 hasConceptScore W2515062708C2778597550 @default.
• W2515062708 hasConceptScore W2515062708C2780026712 @default.
• W2515062708 hasConceptScore W2515062708C32891209 @default.
• W2515062708 hasConceptScore W2515062708C512968161 @default.
• W2515062708 hasConceptScore W2515062708C544153396 @default.
• W2515062708 hasConceptScore W2515062708C58364064 @default.
• W2515062708 hasConceptScore W2515062708C62520636 @default.
• W2515062708 hasConceptScore W2515062708C75473681 @default.
• W2515062708 hasFunder F4320320912 @default.
• W2515062708 hasIssue "42" @default.
• W2515062708 hasLocation W25150627081 @default.
• W2515062708 hasOpenAccess W2515062708 @default.
• W2515062708 hasPrimaryLocation W25150627081 @default.
• W2515062708 hasRelatedWork W2021875819 @default.
• W2515062708 hasRelatedWork W2084892612 @default.
• W2515062708 hasRelatedWork W2092560940 @default.
• W2515062708 hasRelatedWork W2320142918 @default.
• W2515062708 hasRelatedWork W2374462626 @default.
• W2515062708 hasRelatedWork W2379427930 @default.
• W2515062708 hasRelatedWork W2386094688 @default.
• W2515062708 hasRelatedWork W2791102617 @default.
• W2515062708 hasRelatedWork W3175022158 @default.

• next