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• W2515653531 endingPage "137" @default.
• W2515653531 startingPage "132" @default.
• W2515653531 abstract "Two new polyoxometalate(POM)-based entangled coordination networks with chemical formula of [Mn2(H2O)2(BBPTZ)5][SiW12O40] (1) and [Ni2(H2O)2(BBPTZ)5][SiMo12O40]·6H2O (2) (BBPTZ = 4.4′-bis(1,2,4-triazol-1-ylmethyl)biphenyl), were prepared in a hydrothermal reaction system. Compounds 1–2 were characterized by elemental analyses, IR spectroscopy, thermogravimetric analysis, powder X-ray diffraction and single-crystal X-ray diffraction. In compound 1, dangling arms thread in quadrangular window of the adjacent 2-D layers, thus resulting in a rare 2-D → 3-D polythreading motif. Compound 2 exhibits a rare 2-D → 3-D zipper-closing motif. Using the degradation of methylene blue (MB) as the model, the photocatalytic activities of compounds 1–2 were investigated. Both compounds show efficient catalytic activity for the degradation of MB with the order of 2 > 1. It is found that the POM species of compounds 1–2 play the main role in the photocatalytic degradation process." @default.
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• W2515653531 date "2016-10-01" @default.
• W2515653531 modified "2023-09-26" @default.
• W2515653531 title "Two new Keggin-type polyoxometalate-based entangled coordination networks constructed from metal-organic chains with dangling arms" @default.
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• W2515653531 doi "https://doi.org/10.1016/j.inoche.2016.08.013" @default.
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