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• W2515677916 abstract "The syntheses, characterizations and structures of a neutral 2D coordination polymer [Cd(bnzd)(NCS)2]n (1) and a polycationic 3D coordination polymer isolated as perchlorate salt [Cd(bnzd)3]n(ClO4)2n (2) (bnzd = benzidine) are described. X-ray structural analyses reveal that each hexacoordinated cadmium(II) center in 1 adopts a distorted octahedral geometry with a CdN4 S 2 chromophore bound by two N atoms of two different bnzd units and two N and two S atoms of symmetric doubly bridged end-to-end NCS − units extended in a 2D sheet. Six N atoms of six different bridged bnzd units are bonded to each cadmium(II) in 2 in a non-ended fashion affording a 3D network structure. In the crystalline state, each 2D sheet structure in 1 is further stabilized by π⋯π interaction which in turn affords a 3D network structure through multiple intermolecular N-H ⋯S hydrogen bonds. On the other hand, the 3D network structure in 2 is stabilized by weak intermolecular N-H ⋯O hydrogen bonds and C-H ⋯π interactions. Bnzd, 1 and 2 display intraligand 1(π- π*) fluorescence in DMF solution at room temperature. Two cadmium(II) coordination polymers of benzidine with or without thiocyanate afford varied metal-organic frameworks (MOFs) through multiple weak non-covalent forces and are good luminous materials." @default.
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• W2515677916 date "2016-09-01" @default.
• W2515677916 modified "2023-09-26" @default.
• W2515677916 title "Two new hexacoordinated coordination polymers of cadmium(II) containing bridging units only: Syntheses, structures and molecular properties" @default.
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• W2515677916 doi "https://doi.org/10.1007/s12039-016-1153-6" @default.
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