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- W2515728738 endingPage "15068" @default.
- W2515728738 startingPage "15058" @default.
- W2515728738 abstract "By carefully controlling the reaction temperature, treatment of aryl benzyl ethers with tBuLi selectively leads to α-lithiation, generating stable organolithiums that can be directly trapped with a variety of selected electrophiles, before they can undergo the expected [1,2]-Wittig rearrangement. This rearrangement has been deeply studied, both experimentally and computationally, with aryl α-lithiated benzyl ethers bearing different substituents at the aryl ring. The obtained results support the competence of a concerted anionic intramolecular addition/elimination sequence and a radical dissociation/recombination sequence for explaining the tendency of migration for aryl groups. The more favored rearrangements are found for substrates with electron-poor aryl groups that favor the anionic pathway." @default.
- W2515728738 created "2016-09-16" @default.
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- W2515728738 date "2016-09-05" @default.
- W2515728738 modified "2023-10-17" @default.
- W2515728738 title "Exploring the Reactivity of α-Lithiated Aryl Benzyl Ethers: Inhibition of the [1,2]-Wittig Rearrangement and the Mechanistic Proposal Revisited" @default.
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- W2515728738 doi "https://doi.org/10.1002/chem.201602254" @default.
- W2515728738 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27592551" @default.
- W2515728738 hasPublicationYear "2016" @default.
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