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- W2515831438 abstract "A series of highly porous acidic metal–organic framework MIL-101 supported Pd nanoparticles materials with different Pd contents were prepared through a simple sol–gel method. The obtained heterogeneous catalytic material Pd@MIL-101 was comprehensively characterized by powder X-ray diffraction (PXRD), N2 adsorption, FTIR spectroscopy of pyridine adsorption (Py-IR) and transmission electron microscopy (TEM). The intact crystallinity of MIL-101 was found before and after the Pd loading process, and Pd nanoparticles with diameter of 2–3.5 nm were found homogeneously dispersed in MIL-101. The bifunctional Pd@MIL-101 catalyst exhibits good activity in hydrodeoxygenation (HDO) of anisole. It has been shown that the reaction temperature and the Pd content play important roles in the activity toward oxygen-removal. The catalyst after reaction at a high temperature of 240 °C revealed that the Pd nanoparticles tended to migrate to the external surface of the MOF materials and form larger aggregates." @default.
- W2515831438 created "2016-09-16" @default.
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- W2515831438 date "2016-01-01" @default.
- W2515831438 modified "2023-10-11" @default.
- W2515831438 title "Pd@MIL-101 as an efficient bifunctional catalyst for hydrodeoxygenation of anisole" @default.
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- W2515831438 doi "https://doi.org/10.1039/c6ra17756e" @default.
- W2515831438 hasPublicationYear "2016" @default.
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