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• W2516236831 abstract "The use of the bulky cyclopentadienyl ligand Cp′ (Cp′ = C5Me4SiMe3) to stabilize cerium hydrides has resulted in the preparation of two novel tuck-in complexes with C–H activated SiMe3 groups. Subsequent reaction of these with H2 in thf gives a lanthanide terminal hydride species Ce(Cp′)2(H)(thf) which reversibly regenerates the tuck-in complex under sustained vacuum. This compound is only the second structurally characterized terminal cerium hydride. This new hydride is a catalyst in H/D exchange reactions between with both sp3-CH and sp2-CH bonds, and for the hydrogenation of unsaturated alkene bonds." @default.
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• W2516236831 date "2016-09-01" @default.
• W2516236831 modified "2023-09-27" @default.
• W2516236831 title "Reversible Formation of a Cerium-Bound Terminal Hydride: Ce(C5 Me4 SiMe3 )2 (H)(thf)" @default.
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• W2516236831 doi "https://doi.org/10.1002/ejic.201600737" @default.
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