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• W2516754557 endingPage "6363" @default.
• W2516754557 startingPage "6357" @default.
• W2516754557 abstract "Layered transition-metal oxides (Li[NixMnyCoz]O2, NMC, or NMCxyz) due to their poor stability when cycled at a high operating voltage (>4.5 V) have limited their practical applications in industry. Earlier researches have identified Mn(II)-dissolution and some parasitic reactions between NMC surface and electrolyte, especially when NMC is charged to a high potential, as primarily factors responsible for the fading. In our previous work, we have achieved a capacity of NMC active material close to theoretical value and optimized its cycling performance by a depolarized carbon nanotubes (CNTs) network and an unique pre-lithiation process that generates an in situ organic coating (∼40 nm) to prevent Mn(II) dissolution and minimize the parasitic reactions. Unfortunately, this organic coating is not durable enough during a long-term cycling when the cathode operates at a high potential (>4.5 V). This work attempts to improve the surface protection of the NMC532 particles by applying an active inorganic coating consisting of nanosized- and crystal-orientated LiFePO4 (LFP) (about 50 nm, exposed (010) face) to generate a core-shell nanostructure of Li(NixMnyCoz)O2@LiFePO4. Transmission electron microscopy (TEM) and etching X-ray photoelectron spectroscopy have confirmed an intimate contact coating (about 50 nm) between the original structure of NMC and LFP single-particle with atomic interdiffusion at the core-shell interface, and an array of interconnected aligned Li+ tunnels are observed at the interface by cross-sectional high-resolution TEM, which were formed by ball-milling and then strictly controlling the temperature below 100 °C. Batteries based on this modified NMC cathode material show a high reversible capacity when cycled between 3.0 and 4.6 V during a long-term cycling." @default.
• W2516754557 created "2016-09-16" @default.
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• W2516754557 date "2016-09-07" @default.
• W2516754557 modified "2023-10-03" @default.
• W2516754557 title "Aligned Li⁺ Tunnels in Core–Shell Li(Ni_<i>x</i>Mn_<i>y</i>Co_<i>z</i>)O₂@LiFePO₄ Enhances Its High Voltage Cycling Stability as Li-ion Battery Cathode" @default.
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• W2516754557 doi "https://doi.org/10.1021/acs.nanolett.6b02742" @default.
• W2516754557 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27588693" @default.
• W2516754557 hasPublicationYear "2016" @default.
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