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- W2517251323 abstract "The formation and transformation characteristics of ettringite play an extremely important effect on the accelerated hardening and expansion of concrete as well as its long term durability. In alkaline condition, ettringite can be existed stably; but when the alkalinity exceeds a certain value, ettringite can be decomposed into calcium monosulfoaluminate (AFm). In this paper, the stability and its decomposition mechanism of ettringite in alkaline (NH4)2SO4 solution were then investigated. The results show that in alkaline environment, decomposition of ettringite can be occurred and main produces were gypsum and Al(OH)3 as long as the concentration of (NH4)2SO4 reached to a certain extent. Based on experiment data, a kind of NH4+ involved decomposition mechanism of ettringite had been proposed by method of quantum mechanics combined with frontier molecular orbital theory and thermodynamic theory." @default.
- W2517251323 created "2016-09-16" @default.
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- W2517251323 date "2016-10-01" @default.
- W2517251323 modified "2023-10-16" @default.
- W2517251323 title "Stability and decomposition mechanism of ettringite in presence of ammonium sulfate solution" @default.
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- W2517251323 doi "https://doi.org/10.1016/j.conbuildmat.2016.07.135" @default.
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