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- W2517747609 endingPage "12355" @default.
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- W2517747609 abstract "A tetra(carboxylated) PCP pincer ligand has been synthesized as a building block for porous coordination polymers (PCPs). The air- and moisture-stable PCP metalloligands are rigid tetratopic linkers that are geometrically akin to ligands used in the synthesis of robust metal–organic frameworks (MOFs). Here, the design principle is demonstrated by cyclometalation with PdIICl and subsequent use of the metalloligand to prepare a crystalline 3D MOF by direct reaction with CoII ions and structural resolution by single crystal X-ray diffraction. The Pd−Cl groups inside the pores are accessible to post-synthetic modifications that facilitate chemical reactions previously unobserved in MOFs: a Pd−CH3 activated material undergoes rapid insertion of CO2 gas to give Pd−OC(O)CH3 at 1 atm and 298 K. However, since the material is highly selective for the adsorption of CO2 over CO, a Pd−N3 modified version resists CO insertion under the same conditions." @default.
- W2517747609 created "2016-09-16" @default.
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- W2517747609 creator A5073372121 @default.
- W2517747609 creator A5079868859 @default.
- W2517747609 date "2016-08-17" @default.
- W2517747609 modified "2023-09-27" @default.
- W2517747609 title "A PCP Pincer Ligand for Coordination Polymers with Versatile Chemical Reactivity: Selective Activation of CO <sub>2</sub> Gas over CO Gas in the Solid State" @default.
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- W2517747609 doi "https://doi.org/10.1002/anie.201604730" @default.
- W2517747609 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27532740" @default.
- W2517747609 hasPublicationYear "2016" @default.
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