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- W2518262757 abstract "Abstract The reaction of benzyl isocyanide, tert ‐butyl isocyanide, and 2,6‐dimethylphenyl isocyanide with tetramesityldigermene (Mes 2 Ge=GeMes 2 ) was examined. Whereas the addition of benzyl isocyanide gave the C−NC activation product, Mes 2 Ge(CH 2 Ph)Ge(CN)Mes 2 , tert ‐butyl isocyanide, and 2,6‐dimethylphenyl isocyanide did not give stable adducts, rather the rate of conversion of the digermene to the corresponding cyclotrigermane was accelerated. A comparison between the reactivity of the isocyanides with Mes 2 Ge=GeMes 2 and the Ge(100)‐2×1 surface was made and some insights into the surface chemistry are offered." @default.
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- W2518262757 date "2016-08-16" @default.
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- W2518262757 title "Addition of Isocyanides to Tetramesityldigermene: A Comparison of the Reactivity between Surface and Molecular Digermenes" @default.
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- W2518262757 doi "https://doi.org/10.1002/chem.201602222" @default.
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