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• W2519174902 abstract "The CO2 absorption continuum near 2.3 µm is determined for a series of sub atmospheric pressures (250–750 Torr) by high sensitivity Cavity Ring Down Spectroscopy. An experimental procedure consisting in injecting successively a gas flow of CO2 and synthetic air, keeping constant the gas pressure in the CRDS cell, has been developed. This procedure insures a high stability of the spectra baseline by avoiding changes of the optical alignment due to pressure changes. The CO2 continuum was obtained as the difference between the CO2 absorption coefficient and a local lines simulation using a Voigt profile truncated at ±25 cm−1. Following the results of the preceding analysis of the CO2 rovibrational lines (Vasilchenko S et al. J Quant Spectrosc Radiat Transfer 10.1016/j.jqsrt.2016.07.002, a CO2 line list with intensities obtained by variational calculations and empirical line positions was preferred to the HITRAN line list. A quadratic pressure dependence of the absorption continuum is observed, with an average binary absorption coefficient increasing from 2 to 4×10−8 cm−1 amagat−2 between 4320 and 4380 cm−1. The obtained continuum is found in good agreement with a previous measurement using much higher densities (20 amagat) and a low resolution grating spectrograph and is consistent with values currently used in the analysis of Venus spectra." @default.
• W2519174902 created "2016-09-23" @default.
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• W2519174902 date "2017-01-01" @default.
• W2519174902 modified "2023-09-26" @default.
• W2519174902 title "The CO2 absorption spectrum in the 2.3 µm transparency window by high sensitivity CRDS: (II) Self-absorption continuum" @default.
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• W2519174902 doi "https://doi.org/10.1016/j.jqsrt.2016.09.003" @default.
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