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- W2519187427 abstract "Structural iron in sediment clay minerals can be reduced to Fe(II) in situ by treatment with buffered dithionite solutions. The Fe(II) is then available to react with oxidized contaminants in groundwater that passes through the treated zone. Contaminants are removed by reductive precipitation [e.g., Cr(VI)(aq) {r_arrow} Cr(OH){sub 3}(s)] or destroyed by reductive dechlorination (e.g., CCl{sub 4} {r_arrow} reduced C + 4 Cl{sup -}). The effectiveness of the technology depends on several factors including available structural iron in the sediment, porosity of the aquifer, stability of the dithionite solution, and the rates of heterogeneous redox processes. These factors have been studied in a series of experiments ranging from small bench-scale batch and column studies through intermediate-scale transport experiments in a 7-meter-long physical aquifer model to a large-scale pilot field experiment. Each experimental system yields specific types of information that, when integrated, provide a cost-effective means to bring an experimental treatment technology {open_quotes}from the flask to the field.{close_quotes}" @default.
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- W2519187427 date "1995-12-31" @default.
- W2519187427 modified "2023-09-27" @default.
- W2519187427 title "In situ redox manipulation of aquifer sediments for groundwater remediation: From the flask to the field" @default.
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