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• W2519313713 startingPage "16425" @default.
• W2519313713 abstract "Abstract Treatment of the open‐cage fullerene C 63 H 4 NO 2 (Ph) 2 (Py)(N 2 C 6 H 4 ) ( 1 ) with methanol at 150 °C results in an orifice‐enlargement reaction to give C 69 H 8 NO(CO 2 Me)(Ph)(Py)(N 2 C 6 H 4 ) ( 2 ). The overall yield from C 60 to isolated 2 is 6.1 % (four steps). Compound 2 contains a 24‐membered elliptic orifice that spans 8.45 Å along the major axis and 6.37 Å along the minor axis. The skeleton of 2 resembles the hypothetic C 60 H 10 (5,5)‐carbon nanotube endcap. The cup‐shaped structure of 2 is able to include water, hydrogen cyanide, and acetylene, forming H 2 O@ 2 , HCN@ 2 , and C 2 H 2 @ 2 , respectively. The molecular structures of H 2 O@ 2 and HCN@ 2 have been determined by X‐ray crystallography. The 1 H NMR spectra reveal substantial upfield shifts for the endohedral species, such as δ =−10.30 (for H 2 O), −2.74 and −14.26 (for C 2 H 2 ), and −1.22 ppm (for HCN), owing to the strong shielding effects of the fullerene cage." @default.
• W2519313713 created "2016-09-23" @default.
• W2519313713 creator A5007699499 @default.
• W2519313713 creator A5068231747 @default.
• W2519313713 date "2016-10-05" @default.
• W2519313713 modified "2023-10-11" @default.
• W2519313713 title "An Open-Cage Fullerene That Mimics the C₆₀ H₁₀ (5,5)-Carbon Nanotube Endcap to Host Acetylene and Hydrogen Cyanide Molecules" @default.
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• W2519313713 doi "https://doi.org/10.1002/chem.201604114" @default.
• W2519313713 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27616427" @default.
• W2519313713 hasPublicationYear "2016" @default.
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