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• W2519319789 abstract "The hydrolysis of 2-chloro-3,5-dinitropyridine by sodium hydroxide in the presence of micelles of cetyltrimethylammonium bromide (CTABr), cetyltrimethylammonium chloride (CTACl) and sodium dodecyl sulfate (SDS) has been studied. The reaction follows a consecutive reaction path involving the formation of a long-lived intermediate 3 and finally giving the product, 3,5-dinitro 2-pyridone 2. The mechanism follows an addition of the nucleophile, ring opening and ring closure (ANRORC) reaction path. The rate constant was observed to be first-order dependent on [OH−]. The rate of reaction increased on increasing [CTABr] and, after reaching to the maxima, it started decreasing. The anionic SDS micelles inhibited the rate of hydrolysis. The results of the kinetic experiments were treated with the help of the pseudophase ion exchange model and the Menger–Portnoy model. The added salts, viz. NaBr, Na-toluene-4-sulphonate, and (CH3)4NBr on varying [CTACl] and [SDS] inhibited the rate of reaction. The various kinetic parameters in the presence and absence of salts were determined and are reported herewith. Copyright © 2011 John Wiley & Sons, Ltd." @default.
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• W2519319789 date "2012-01-09" @default.
• W2519319789 modified "2023-09-27" @default.
• W2519319789 title "Micellar effects on aromatic nucleophilic substitution by the ANRORC mechanism. Hydrolysis of 2-chloro-3,5-dinitropyridine" @default.
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• W2519319789 doi "https://doi.org/10.1002/poc.2908" @default.
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