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- W2519387617 abstract "Kahalalide B 4a and its analogues 4b-e were synthesized via solid-phase peptide synthesis on silica and imidazole-catalyzed macrolactonization. Thus, the peptide immobilization onto the functionalized mercaptophenyl silica gel 1 followed by removal of the resin support and the O-protecting group gave the peptide thioester 3. Imidazole (1.5 M) catalyzed the macrolactonization of 3 to afford the corresponding cyclic depsipeptides 4 in 80-98% yield." @default.
- W2519387617 created "2016-09-23" @default.
- W2519387617 date "2010-07-22" @default.
- W2519387617 modified "2023-09-26" @default.
- W2519387617 title "Silica-Phase Synthesis of Kahalalide B and Its Analogues" @default.
- W2519387617 doi "https://doi.org/10.1055/s-0030-1257797" @default.
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