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- W2519642006 abstract "(+)-Yaoshanenolide B was synthesized employing as a key step an endo- and face-selective Diels–Alder reaction between natural R-(−)-α-phellandrene and the exocyclic double bond of a 5-methylene-2(5H)-furanone. The dienophile furanone was prepared by photooxygenation of a suitably substituted 2-thiophenylfuran followed by dehydration of the resulting γ-hydroxybutenolide. Through this synthesis, the initially proposed structure for (+)-yaoshanenolide B has been revised to the 1R,2S,4R,7R,1″S diastereomer." @default.
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- W2519642006 date "2016-09-13" @default.
- W2519642006 modified "2023-09-26" @default.
- W2519642006 title "Total Synthesis and Structural Revision of (+)-Yaoshanenolide B" @default.
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- W2519642006 doi "https://doi.org/10.1021/acs.orglett.6b02446" @default.
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