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• W2519700647 abstract "A direct asymmetric Friedel–Crafts (F–C) alkylation reaction between a wide range of indoles and ethyl 2-(4-methoxyphenylimino)acetate catalyzed by Trost’s dinuclear complex is reported. A series of 3-indolylglycine derivatives were synthesized in enantioselectivity of up to >99% enantiomeric excess (ee) using 10 mol% catalyst loading under mild conditions. This atom economic reaction could be run on a gram scale without impacting its enantioselectivity. The absolute stereochemistry of catalytic products was determined by correlation with a known configuration compound. A possible mechanism was proposed for the asymmetric induction." @default.
• W2519700647 created "2016-09-23" @default.
• W2519700647 creator A5004335358 @default.
• W2519700647 creator A5005801799 @default.
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• W2519700647 date "2016-09-27" @default.
• W2519700647 modified "2023-10-17" @default.
• W2519700647 title "Synthesis of 3-Indolylglycine Derivatives via Dinuclear Zinc Catalytic Asymmetric Friedel–Crafts Alkylation Reaction" @default.
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• W2519700647 doi "https://doi.org/10.1021/acs.joc.6b01805" @default.
• W2519700647 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27626632" @default.
• W2519700647 hasPublicationYear "2016" @default.
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