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- W2520039993 abstract "Abstract A diastereoselective [3 + 2] cycloaddition of N ‐aryl substituted maleimides with N , α ‐diphenyl nitrone possessing 11‐hydroxyundecyloxy as a flexible substituent was performed. Experimental and comprehensive mechanistic density functional theory studies reveals that intermolecular H‐bonding and steric repulsive interaction predominate exo‐Z and exo‐E cycloaddition transition states, respectively. The reaction proceeded smoothly depending on the reactants and gave a good yield of ( syn ) cis ‐isoxazolidine or ( anti ) trans ‐isoxazolidine as a single diastereomer." @default.
- W2520039993 created "2016-09-23" @default.
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- W2520039993 date "2016-09-08" @default.
- W2520039993 modified "2023-10-16" @default.
- W2520039993 title "High diastereoselectivity induced by intermolecular hydrogen bonding in [3 + 2] cycloaddition reaction: experimental and computational mechanistic approaches" @default.
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- W2520039993 doi "https://doi.org/10.1002/poc.3629" @default.
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