Matches in SemOpenAlex for { <https://semopenalex.org/work/W2520123046> ?p ?o ?g. }
- W2520123046 endingPage "3634" @default.
- W2520123046 startingPage "3626" @default.
- W2520123046 abstract "Polysilanes upon UV irradiation give rise to silyl macroradicals which are capable to initiate radical polymerization. Hence, chiral block functional polysilanes were synthesized by UV irradiation of poly(methylphenylsilane) (PMPS) with a vinyl chiral monomer, (R)-N-(1-phenylethyl)methacrylamide (R-NPEMAM). The synthesized copolymer samples were characterized by FTIR, NMR, and UV–vis spectroscopy. The number and weight average molecular weights of PMPS and synthesized chiral-block-PMPS were measured by GPC analysis. Two glass transition temperatures (Tg) of the synthesized materials clearly indicate the formation of chiral-block-PMPS copolymers. SEM analysis also indicated the synthesized organic–inorganic block copolymers. The optical and chiroptical properties of the synthesized materials were studied. The cotton effect is observed not only at 276 nm due to aromatic ring of the chiral monomer units but also at 325 nm which is associated with the Si–Si conjugation of PMPS block of synthesized functional polysilanes. Such tunable chirality may find potential application in optoelectronics. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016, 54, 3626–3634" @default.
- W2520123046 created "2016-09-23" @default.
- W2520123046 creator A5005944017 @default.
- W2520123046 creator A5008208175 @default.
- W2520123046 creator A5080492082 @default.
- W2520123046 date "2016-09-15" @default.
- W2520123046 modified "2023-10-12" @default.
- W2520123046 title "Synthesis of organic-inorganic chiral block poly(methylphenylsilane) functional polymers, and study of their optical and chiroptical properties" @default.
- W2520123046 cites W1968696958 @default.
- W2520123046 cites W1969348141 @default.
- W2520123046 cites W1975388720 @default.
- W2520123046 cites W1975754865 @default.
- W2520123046 cites W1985866377 @default.
- W2520123046 cites W1986319056 @default.
- W2520123046 cites W1986471276 @default.
- W2520123046 cites W1986692373 @default.
- W2520123046 cites W1988168939 @default.
- W2520123046 cites W1991289402 @default.
- W2520123046 cites W2005723149 @default.
- W2520123046 cites W2006121333 @default.
- W2520123046 cites W2007376692 @default.
- W2520123046 cites W2007507643 @default.
- W2520123046 cites W2010831437 @default.
- W2520123046 cites W2010869687 @default.
- W2520123046 cites W2010941569 @default.
- W2520123046 cites W2014419600 @default.
- W2520123046 cites W2015878675 @default.
- W2520123046 cites W2021460551 @default.
- W2520123046 cites W2022257365 @default.
- W2520123046 cites W2026030370 @default.
- W2520123046 cites W2029432116 @default.
- W2520123046 cites W2029764197 @default.
- W2520123046 cites W2029851331 @default.
- W2520123046 cites W2030031070 @default.
- W2520123046 cites W2031189870 @default.
- W2520123046 cites W2032976475 @default.
- W2520123046 cites W2033297392 @default.
- W2520123046 cites W2037950234 @default.
- W2520123046 cites W2040728588 @default.
- W2520123046 cites W2047593372 @default.
- W2520123046 cites W2047672691 @default.
- W2520123046 cites W2047770192 @default.
- W2520123046 cites W2048738126 @default.
- W2520123046 cites W2053754779 @default.
- W2520123046 cites W2056586674 @default.
- W2520123046 cites W2057946662 @default.
- W2520123046 cites W2058612271 @default.
- W2520123046 cites W2060957696 @default.
- W2520123046 cites W2063727422 @default.
- W2520123046 cites W2064091664 @default.
- W2520123046 cites W2065379475 @default.
- W2520123046 cites W2066697261 @default.
- W2520123046 cites W2069226234 @default.
- W2520123046 cites W2073498009 @default.
- W2520123046 cites W2076043962 @default.
- W2520123046 cites W2082587127 @default.
- W2520123046 cites W2083944003 @default.
- W2520123046 cites W2084315679 @default.
- W2520123046 cites W2084981992 @default.
- W2520123046 cites W2086235232 @default.
- W2520123046 cites W2087687597 @default.
- W2520123046 cites W2090224001 @default.
- W2520123046 cites W2109013442 @default.
- W2520123046 cites W2111072755 @default.
- W2520123046 cites W2131853197 @default.
- W2520123046 cites W2138095279 @default.
- W2520123046 cites W2139336024 @default.
- W2520123046 cites W2141099217 @default.
- W2520123046 cites W2145818865 @default.
- W2520123046 cites W2163887121 @default.
- W2520123046 cites W2206445882 @default.
- W2520123046 cites W2418818189 @default.
- W2520123046 cites W1983673536 @default.
- W2520123046 cites W2059319558 @default.
- W2520123046 doi "https://doi.org/10.1002/pola.28251" @default.
- W2520123046 hasPublicationYear "2016" @default.
- W2520123046 type Work @default.
- W2520123046 sameAs 2520123046 @default.
- W2520123046 citedByCount "4" @default.
- W2520123046 countsByYear W25201230462017 @default.
- W2520123046 countsByYear W25201230462019 @default.
- W2520123046 countsByYear W25201230462023 @default.
- W2520123046 crossrefType "journal-article" @default.
- W2520123046 hasAuthorship W2520123046A5005944017 @default.
- W2520123046 hasAuthorship W2520123046A5008208175 @default.
- W2520123046 hasAuthorship W2520123046A5080492082 @default.
- W2520123046 hasConcept C121332964 @default.
- W2520123046 hasConcept C124668440 @default.
- W2520123046 hasConcept C15920480 @default.
- W2520123046 hasConcept C166940927 @default.
- W2520123046 hasConcept C178790620 @default.
- W2520123046 hasConcept C185592680 @default.
- W2520123046 hasConcept C188027245 @default.
- W2520123046 hasConcept C192562407 @default.
- W2520123046 hasConcept C20621625 @default.
- W2520123046 hasConcept C2775961978 @default.
- W2520123046 hasConcept C2779402116 @default.
- W2520123046 hasConcept C44228677 @default.