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- W2520359771 abstract "Abstract A method for fabricating high‐efficiency Cu 2 ZnSn(S,Se) 4 (CZTSSe) solar cells is presented, and it is based on a non‐explosive, low‐cost, and simple solution process followed by a two‐step heat treatment. 2‐Methoxyethanol was used as a solvent, and Cu, Zn, Sn, chloride salts, and thiourea were used as solutes. A CZTSSe absorber was prepared by sulfurising and then selenising an as‐coated Cu 2 ZnSnS 4 (CZTS) film. Sulfurisation in a sulfur vapour filled furnace for a long time (2 h) enhanced the crystallisation of the as‐coated CZTS film and improved the stability of the CZTS precursor, and selenisation promoted further grain growth to yield a void‐free CZTSSe film. Segregation of Cu and S at the grain boundaries, the absence of a fine‐grain bottom layer, and the large grain size of the CZTSSe absorber were the main factors that enhanced the grain‐to‐grain transport of carriers and consequently the short‐circuit current ( J sc ) and efficiency. The efficiency of the CZTS solar cell was 5.0%, which increased to 10.1% after selenisation. For the 10.1% CZTSSe solar cell, the external quantum efficiency was approximately 80%, the open‐circuit voltage was 450 mV, the short‐circuit current was 36.5 mA/cm 2 , and the fill factor was 61.9%. Copyright © 2016 John Wiley & Sons, Ltd." @default.
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- W2520359771 date "2016-09-06" @default.
- W2520359771 modified "2023-10-18" @default.
- W2520359771 title "High-efficiency Cu<sub>2</sub>ZnSn(S,Se)<sub>4</sub>solar cells fabricated through a low-cost solution process and a two-step heat treatment" @default.
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- W2520359771 doi "https://doi.org/10.1002/pip.2810" @default.
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