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- W2520542655 abstract "Silicon-alloys are candidates for anode materials of high capacity lithium-ion batteries. Here we report the mechanical milling (mechanical alloying) synthesis of various silicon-alloy samples. The samples have been characterized by X-ray diffraction, scanning electron and transmission electron microscopies, and electrochemical tests to investigate their electrochemical lithium insertion-extraction performance. The metallic elements added during alloying such as Ni, Co, Cu, and Zr are found to be effective for nanocrystallization or amorphization of silicon alloy. Especially Si-Sn-Cu alloy has high 1st lithium storage capacity of 2690 mAh g−1 with a coulombic efficiency of 85% and relatively long cycle life. The changes of Si-Sn-Cu alloy composite electrode in volume and structure were also investigated to obtain insights for practical electrode design." @default.
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- W2520542655 date "2015-01-01" @default.
- W2520542655 modified "2023-10-04" @default.
- W2520542655 title "Mechanical Milling Synthesis and Electrochemical Evaluation of Silicon-transition Metal Alloy Anode Materials for Lithium-ion Batteries" @default.
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- W2520542655 doi "https://doi.org/10.5796/electrochemistry.83.445" @default.
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