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- W2521182014 abstract "We performed an extensive study on Nafion 117 membrane imbibed with various concentrations of aqueous ammonium metavanadate (NH4VO3), and vanadyl sulfate (VOSO4), in 2 M H2SO4 over the temperature range of 20–100 °C, using 1H NMR and AC Impedance spectroscopies. The objective was to determine the effect of the tetravalent (VO2+) and pentavalent (VO2+) vanadium ions on the proton transport of Nafion 117.1H NMR chemical shift and linewidth data show greater short-range proton transport for the VO2+ imbibed membranes compared with the VO2+. However, the local environments seem to differ in that while the data for VO2+ imbibed membranes seem to follow more the trends observed for water hydrated Nafion 117, those for the VO2+ followed the trend of its aqueous bulk vanadium solvents, indicating that viscosity plays a larger role for the VO2+ imbibed membranes compared to the VO2+." @default.
- W2521182014 created "2016-09-30" @default.
- W2521182014 creator A5048741293 @default.
- W2521182014 creator A5064904298 @default.
- W2521182014 date "2016-11-01" @default.
- W2521182014 modified "2023-10-18" @default.
- W2521182014 title "Mediated proton transport through Nafion 117 membranes imbibed with varying concentrations of aqueous VOSO4 (VO2+) and NH4VO3 (VO2+) in 2 M H2SO4" @default.
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- W2521182014 doi "https://doi.org/10.1016/j.jpowsour.2016.09.088" @default.
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