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- W2521944528 abstract "Effects of Co doping on the crystal structure, magnetic, electrical transport properties, and magnetocaloric effect (MCE) of antiperovskite ZnCFe3−xCox (0 ≤ x ≤ 3) were investigated. The value of lattice constant decreases with increasing x. The Curie temperature (TC) decreases from 358 K in ZnCFe3 to 5 K in ZnCCo3 and the saturated magnetization declines monotonously. The reduced ferromagnetic state is explained by the band filling effect resulted from the Co substitution. For x ≥ 2.3, the negative magnetoresistance (MR) below TC starts to increase as x or magnetic field increases, reaching −16% for x = 2.9 under H = 45 kOe, which is three times larger than that of GaCMn3 at 250 K. MCE was investigated for selected compositions. The temperature range of MCE is tuned covering 5–350 K as a function of Co-level. Although the maximal entropy change decreases a little with increasing x, the refrigeration ranges across room temperature. At the optimal composition x = 0.5, TC is 312 K with a magnetic entropy change of 2.09 J/kg K and relative cooling power (RCP) of 283 J/kg (ΔH = 45 kOe), make it a room-temperature MCE candidate." @default.
- W2521944528 created "2016-09-30" @default.
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- W2521944528 date "2017-02-01" @default.
- W2521944528 modified "2023-10-15" @default.
- W2521944528 title "Magnetic and structural phase diagram of antiperovskites ZnCFe3−Co (0 ≤ x ≤ 3): The combined negative magnetoresistance and large room-temperature magnetocaloric effect in x = 0.5" @default.
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- W2521944528 doi "https://doi.org/10.1016/j.jallcom.2016.09.241" @default.
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