Matches in SemOpenAlex for { <https://semopenalex.org/work/W2522167139> ?p ?o ?g. }
Showing items 1 to 96 of
96
with 100 items per page.
- W2522167139 endingPage "194" @default.
- W2522167139 startingPage "188" @default.
- W2522167139 abstract "The reaction of AuCl(tht) with the diphosphine donors 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd) and 2,3-bis(diphenylphosphino)-N-phenylmaleimide (bmi) in a 2:1 stoichiometry affords the diphosphine-bridged digold(I) complexes Au2Cl2(bpcd) (1) and Au2Cl2(bmi) (2), respectively. 1 and 2 have been isolated and characterized in solution by IR and NMR spectroscopy (1H and 31P), and the solid-state structures established by X-ray crystallography. The X-Au-Au-X (X = Cl, P) atoms in both Au2 dimers exhibit a gauche-type (staggered) interaction based on a torsion angle of −54° for 1 (X = Cl) and −70° for 2 (X = Cl, mean angle for the two independent molecules). Each Au2 product displays a weak aurophilic interaction based on a Au-Au internuclear distance on the order of 2.9 Å. The bonding in 1 and 2 has been investigated by electronic structure calculations and the composition of the HOMO and LUMO levels determined in the case of 2. The potential energy surface for the interconversion of 2 to an alternative staggered conformation has been computed, and this transformation takes place through an eclipsed transition structure. The preference for a structure that contains a staggered orientation of Cl-Au-Au-Cl and P-Au-Au-Cl atoms is discussed." @default.
- W2522167139 created "2016-09-30" @default.
- W2522167139 creator A5047083341 @default.
- W2522167139 creator A5049134667 @default.
- W2522167139 creator A5055350677 @default.
- W2522167139 creator A5073687567 @default.
- W2522167139 date "2017-02-01" @default.
- W2522167139 modified "2023-10-12" @default.
- W2522167139 title "Diphosphine-bridged digold(I) compounds: Structural and computational studies on the aurophilic interaction in Au2Cl2(μ-bpcd) and Au2Cl2(μ-bmi)" @default.
- W2522167139 cites W1605467703 @default.
- W2522167139 cites W1618970147 @default.
- W2522167139 cites W1964486204 @default.
- W2522167139 cites W1965272987 @default.
- W2522167139 cites W1965991116 @default.
- W2522167139 cites W1966792574 @default.
- W2522167139 cites W1967423141 @default.
- W2522167139 cites W1981745234 @default.
- W2522167139 cites W1992821091 @default.
- W2522167139 cites W1998851175 @default.
- W2522167139 cites W1999695539 @default.
- W2522167139 cites W2009097215 @default.
- W2522167139 cites W2009202316 @default.
- W2522167139 cites W2016686896 @default.
- W2522167139 cites W2017929292 @default.
- W2522167139 cites W2018191649 @default.
- W2522167139 cites W2019064975 @default.
- W2522167139 cites W2023271753 @default.
- W2522167139 cites W2030841140 @default.
- W2522167139 cites W2033430228 @default.
- W2522167139 cites W2034188640 @default.
- W2522167139 cites W2038767330 @default.
- W2522167139 cites W2042944554 @default.
- W2522167139 cites W2049746069 @default.
- W2522167139 cites W2052573265 @default.
- W2522167139 cites W2063450118 @default.
- W2522167139 cites W2064004505 @default.
- W2522167139 cites W2069697794 @default.
- W2522167139 cites W2078686410 @default.
- W2522167139 cites W2086679247 @default.
- W2522167139 cites W2086791656 @default.
- W2522167139 cites W2114646840 @default.
- W2522167139 cites W2127195103 @default.
- W2522167139 cites W2143981217 @default.
- W2522167139 cites W2147626487 @default.
- W2522167139 cites W2160539353 @default.
- W2522167139 cites W2263587925 @default.
- W2522167139 cites W2467724368 @default.
- W2522167139 cites W2474873634 @default.
- W2522167139 doi "https://doi.org/10.1016/j.molstruc.2016.09.068" @default.
- W2522167139 hasPublicationYear "2017" @default.
- W2522167139 type Work @default.
- W2522167139 sameAs 2522167139 @default.
- W2522167139 citedByCount "3" @default.
- W2522167139 countsByYear W25221671392018 @default.
- W2522167139 countsByYear W25221671392019 @default.
- W2522167139 crossrefType "journal-article" @default.
- W2522167139 hasAuthorship W2522167139A5047083341 @default.
- W2522167139 hasAuthorship W2522167139A5049134667 @default.
- W2522167139 hasAuthorship W2522167139A5055350677 @default.
- W2522167139 hasAuthorship W2522167139A5073687567 @default.
- W2522167139 hasBestOaLocation W25221671391 @default.
- W2522167139 hasConcept C112887158 @default.
- W2522167139 hasConcept C178790620 @default.
- W2522167139 hasConcept C185592680 @default.
- W2522167139 hasConcept C32909587 @default.
- W2522167139 hasConcept C71240020 @default.
- W2522167139 hasConcept C8010536 @default.
- W2522167139 hasConcept C89025888 @default.
- W2522167139 hasConceptScore W2522167139C112887158 @default.
- W2522167139 hasConceptScore W2522167139C178790620 @default.
- W2522167139 hasConceptScore W2522167139C185592680 @default.
- W2522167139 hasConceptScore W2522167139C32909587 @default.
- W2522167139 hasConceptScore W2522167139C71240020 @default.
- W2522167139 hasConceptScore W2522167139C8010536 @default.
- W2522167139 hasConceptScore W2522167139C89025888 @default.
- W2522167139 hasFunder F4320306196 @default.
- W2522167139 hasLocation W25221671391 @default.
- W2522167139 hasOpenAccess W2522167139 @default.
- W2522167139 hasPrimaryLocation W25221671391 @default.
- W2522167139 hasRelatedWork W111429041 @default.
- W2522167139 hasRelatedWork W1580628924 @default.
- W2522167139 hasRelatedWork W2061552628 @default.
- W2522167139 hasRelatedWork W2185950937 @default.
- W2522167139 hasRelatedWork W2394937833 @default.
- W2522167139 hasRelatedWork W2414458849 @default.
- W2522167139 hasRelatedWork W2420782624 @default.
- W2522167139 hasRelatedWork W2518493746 @default.
- W2522167139 hasRelatedWork W2560727280 @default.
- W2522167139 hasRelatedWork W2590591644 @default.
- W2522167139 hasVolume "1129" @default.
- W2522167139 isParatext "false" @default.
- W2522167139 isRetracted "false" @default.
- W2522167139 magId "2522167139" @default.
- W2522167139 workType "article" @default.