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• W2522366156 abstract "Abstract In a continuation of previous studies, thermophysical properties of the systems containing aspirin (ASA), ionic liquid, 1-octyl-3-methylimidazolium bromide ([OMIM][Br]) and acetonitrile (MeCN) have been determined. These properties contain density, viscosity, speed of sound and refractive index measured at T =(288.15 K–318.15 K) and at atmospheric pressure. The measured data have been applied to calculate the apparent molar volumes at infinite dilution <m:math xmlns:m=http://www.w3.org/1998/Math/MathML> <m:mrow> <m:msubsup> <m:mi>V</m:mi> <m:mi>φ</m:mi> <m:mn>0</m:mn> </m:msubsup> <m:mo>,</m:mo> </m:mrow> </m:math> $V_varphi ^0,$ transfer volumes <m:math xmlns:m=http://www.w3.org/1998/Math/MathML> <m:mrow> <m:mi>Δ</m:mi> <m:msubsup> <m:mi>V</m:mi> <m:mi>φ</m:mi> <m:mn>0</m:mn> </m:msubsup> <m:mo>,</m:mo> </m:mrow> </m:math> $Delta V_varphi ^0,$ apparent molar isentropic compressibilities κ ϕ , to viscosity B -coefficients and solvation number. The positive values of <m:math xmlns:m=http://www.w3.org/1998/Math/MathML> <m:mrow> <m:mi>Δ</m:mi> <m:msubsup> <m:mi>V</m:mi> <m:mi>φ</m:mi> <m:mn>0</m:mn> </m:msubsup> </m:mrow> </m:math> $Delta V_varphi ^0$ and <m:math xmlns:m=http://www.w3.org/1998/Math/MathML> <m:mrow> <m:mi>Δ</m:mi> <m:msubsup> <m:mi>κ</m:mi> <m:mi>φ</m:mi> <m:mn>0</m:mn> </m:msubsup> </m:mrow> </m:math> $Delta kappa _varphi ^0$ indicate that dominant interactions between ASA and ionic liquid are ion–polar and polar–polar interactions. From the obtained parameters, some information in regard with the solute–solvent interactions in the studied systems was obtained. The cosphere overlap model was used to interpret the positive transfer volume <m:math xmlns:m=http://www.w3.org/1998/Math/MathML> <m:mrow> <m:mi>Δ</m:mi> <m:msubsup> <m:mi>V</m:mi> <m:mi>φ</m:mi> <m:mn>0</m:mn> </m:msubsup> <m:mo>.</m:mo> </m:mrow> </m:math> $Delta V_varphi ^0.$" @default.
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• W2522366156 date "2016-09-17" @default.
• W2522366156 modified "2023-10-14" @default.
• W2522366156 title "Volumetric, Ultrasonic and Viscometric Studies of Aspirin in the Presence of 1-Octyl-3-Methylimidazolium Bromide Ionic Liquid in Acetonitrile Solutions at T=(288.15–318.15) K" @default.
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• W2522366156 doi "https://doi.org/10.1515/zpch-2015-0723" @default.
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