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- W2522497415 abstract "Abstract. The crystal structures of two classical cobalt(III) complexes comprising the [CoCl(NH3)(en)(py)2]2+ cation were determined by single-crystal X-ray diffraction. Both complexes, dark red [CoCl(NH3)(en)(py)2]Cl2·H2O (1) and purple [CoCl(NH3)-(en)(py)2][HgCl4]·1.125H2O (2), crystallize in the triclinic space group P1. In both compounds, the Co atom exhibits a typical octahedral coordination and the configuration index of the complex is OC-6-43. In the case of the chloride (1), the asymmetric unit comprises one formula unit, whereas there are two formula units in the case of the tetrachloridomercurate (2). Complex cations, anions, and crystal water molecules are interconnected by various N–H···N, N–H···Cl, N–H···O, O–H···Cl, and O–H···O bridge bonds. As a result, compound 1 features a two-dimensional layer structure and compound 2 exists as a three-dimensional network." @default.
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- W2522497415 date "2016-10-01" @default.
- W2522497415 modified "2023-09-27" @default.
- W2522497415 title "Crystal Structures and Hydrogen Bonding of Two Complexes containing the [Ammine-chlorido-ethylenediamine-bis(pyridine)cobalt(III)]2+Cation" @default.
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- W2522497415 doi "https://doi.org/10.1002/zaac.201600251" @default.
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