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• W2522785735 abstract "An efficient route to obtain allyl- and propargyl-containing diols from 10-undecen-1-ol, and their polymerization with isophorone diisocyanate to produce alkene- and alkyne-functionalized polyurethanes (PUs) is described. The bio-based PUs have been further modified by thiol-ene/yne coupling of thioglycerol into unsaturation to obtain a series of PUs with enhanced hydrophilicity. All the synthesized PUs were characterized by FTIR-ATR and NMR spectroscopy. As expected, the PUs were amorphous and DSC revealed glass transition temperatures in the range of 40 °C–5 °C for the PUs before and after modification. The PUs exhibited highly tunable thermal and mechanical properties. The mechanical properties of these bio-based polymers (E modulus from 774 MPa to 6 MPa and at break from 45% to 401%) make the suitable materials for a large range of applications." @default.
• W2522785735 created "2016-09-30" @default.
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• W2522785735 date "2016-10-01" @default.
• W2522785735 modified "2023-09-24" @default.
• W2522785735 title "Synthesis of castor-oil based polyurethanes bearing alkene/alkyne groups and subsequent thiol-ene/yne post-modification" @default.
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• W2522785735 doi "https://doi.org/10.1016/j.polymer.2016.09.057" @default.
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