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- W2522871868 abstract "Chemisorption of H2, O2, and N2O at 443 K as well as XRD and TEM techniques were used to characterize small (3–4 nm) silver crystallites supported on η-Al2O3. The effects of different pretreatment procedures were also examined. The amounts of chemisorbed H2 on reduced Ag surfaces were insignificant (<10% of the O-monolayer). Adsorption-decomposition of N2O according to the following reaction:N2O(g)+Ags→Ags-Oa+N2(g)provides oxygen coverages similar to those obtained using O2 as the adsorbate. In either case, the adsorbed oxygen layer can be stoichiometrically titrated with H2 at 443 K by the reaction:Ags-Oa+H2(g)→Ags+H2O(ads)after correction for the small amount of hydrogen adsorption which occurs on reduced silver surfaces. This titration reaction provides significant advantages for characterizing silver catalysts, which are discussed." @default.
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- W2522871868 date "1984-12-01" @default.
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- W2522871868 title "Characterization of Supported Silver Catalysts II. Adsorption Studies of Well-Dispersed Ag on η-Al2O3" @default.
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- W2522871868 doi "https://doi.org/10.1177/026361748400100401" @default.
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