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- W2522916615 abstract "Solid-state reactions occur primarily at the interfaces of heterogenous systems and little is known about how these reactions proceed. In conventional solid-state synthetic approaches, there is no change to control the kinetics of the reaction because high reaction temperatures are needed to overcome slow diffusion of the reactants. This study focuses upon the low-temperature reaction of niobium-silicon superlattices. In superlattice reactants, slow rates of solid-state reaction at low temperatures are overcome by reducing the diffusion distances. The evolution of interfacial structure in niobium-silicon superlattices with temperature and time was investigated by taking advantage of the low-angle diffraction peaks directly monitors interfacial structure. By reducing the layer thicknesses within the superlattice, nucleation of NbSi{sub 2} at the interface between niobium and silicon was prevented." @default.
- W2522916615 created "2016-09-30" @default.
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- W2522916615 date "1993-12-31" @default.
- W2522916615 modified "2023-09-27" @default.
- W2522916615 title "The solid-state reaction of niobium and silicon at low temperatures: Control of reaction kinetics using superlattice reactants" @default.
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