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• W2523576375 endingPage "13141" @default.
• W2523576375 startingPage "13137" @default.
• W2523576375 abstract "A catalytic strategy was developed for asymmetric substitution reactions at sp3 -hybridized carbon atoms by using a chiral alkylating agent generated in situ from trichloroacetimidate and a chiral phosphoric acid. The resulting chiral p-methoxybenzyl phosphate selectively reacts with β-amino alcohols rather than those without a β-NH functionality. The use of an electronically and sterically tuned chiral phosphoric acid enables the kinetic resolution of amino alcohols through p-methoxybenzylation with good enantioselectivity." @default.
• W2523576375 created "2016-09-30" @default.
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• W2523576375 date "2016-10-06" @default.
• W2523576375 modified "2023-10-14" @default.
• W2523576375 title "Use of a Catalytic Chiral Leaving Group for Asymmetric Substitutions at sp³ -Hybridized Carbon Atoms: Kinetic Resolution of β-Amino Alcohols by <i>p</i> -Methoxybenzylation" @default.
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• W2523576375 doi "https://doi.org/10.1002/anie.201607208" @default.
• W2523576375 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27709822" @default.
• W2523576375 hasPublicationYear "2016" @default.
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