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• W2523606558 endingPage "5129" @default.
• W2523606558 startingPage "5126" @default.
• W2523606558 abstract "A new synthetic route to (−)-neocosmosin A was devised by elaboration of intramolecular Diels–Alder (IMDA) cycloaddition of 2-pyrone containing a bromopropiolate group as the dienophile. The IMDA reaction was accompanied by cycloreversion of carbon dioxide to give benzannulated macrolide with two bromide groups at C14 and C16. Installation of the pinacolboryl groups and oxidations allowed completion of the total synthesis of (−)-neocosmosin A." @default.
• W2523606558 created "2016-09-30" @default.
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• W2523606558 date "2016-09-20" @default.
• W2523606558 modified "2023-10-17" @default.
• W2523606558 title "Total Synthesis of (−)-Neocosmosin A via Intramolecular Diels–Alder Reaction of 2-Pyrone" @default.
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• W2523606558 doi "https://doi.org/10.1021/acs.orglett.6b02575" @default.
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