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• W2523640733 abstract "Triphenylborane (BPh3 ) was found to catalyze the reduction of tertiary amides with hydrosilanes to give amines under mild condition with high chemoselectivity in the presence of ketones, esters, and imines. N,N-Dimethylacrylamide was reduced to provide the α-silyl amide. Preliminary studies indicate that the hydrosilylation catalyzed by BPh3 may be mechanistically different from that catalyzed by the more electrophilic B(C6 F5 )3 ." @default.
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• W2523640733 date "2016-10-06" @default.
• W2523640733 modified "2023-10-10" @default.
• W2523640733 title "Chemoselective Reduction of Tertiary Amides to Amines Catalyzed by Triphenylborane" @default.
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• W2523640733 doi "https://doi.org/10.1002/anie.201605236" @default.
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