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- W2524287462 abstract "Corrosion protective property of various ferrite paint films was investigated from a viewpoint of the chemical property (measurement of distribution of basic strength on the surface of pigment) of the ferrite pigment (MO·Fe2O3, M=Mg, Ca, Sr, Ba, Fe, Zn) and its interaction (impedance measurement, IR spectra, and thermal analysis) with silicone resin binder. As for each of the pigments, the steel plate electrode coated with the paint of 4:2 showed the largest film resistance (Rf) and the smallest film capacitance (Cf). In particular, paint films of any mixture ratio showed the difference in the corrosion protective property even at the initial stage after immersion. The values of Cf for 4:1 of Mg, Sr, 4:2 of Sr, Ba, Fe, and 4:3 of Ba ferrite paint films were smaller than that of blank, i. e. Cf=10-9F/cm2. Therefore, these paint films are believed to intercept well the permeation of water into itself. IR and thermal analysis of paints revealed that the addition of pigments clearly leads to the decrease of silanol group in binder. Thus, it was concluded that the crosslinkability of silicone resin proceeded and the result was effectively responsible for the anti-permeability of water into the films. From the measurement of basicity, mol number of all of the basic centers of pigment situated in these paint films was 1-2mmol (H0>+1.5). The corrosion protective property of paint film was found to be governed by the mol number of basicity center in paint film." @default.
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- W2524287462 date "1988-01-01" @default.
- W2524287462 modified "2023-10-16" @default.
- W2524287462 title "Corrosion Protective Property of Ferrite Paint Films with Silicone Resin Binder" @default.
- W2524287462 doi "https://doi.org/10.3323/jcorr1974.37.8_485" @default.
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