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- W252506597 abstract "Abstract The microwave spectrum of 1,1-difluoro-l-silacyclopent-3-ene has been recorded from 26.5 to 40.0 GHz. Only A -type transitions were observed. The R -branch assignments have been made for the ground state and the first three excited states of the ring puckering vibration. It is shown that the five-membered ring structure is planar from the values of the components of the dipole moment, as well as from the value of the inertial defect as a function of the ring puckering quantum number. From the relative intensity measurements, it is concluded that the first excited state of the ring puckering vibration has a frequency of 38 ±7 cm −1 and that the vibration is nearly harmonic. The components of the dipole moment were determined by the Stark effect to be μ a = 2.02 ±0.06 D, μ b = 0, and μ c = 0.0 ±0.09 D. All of the observed data are consistent with a molecule of C 2v symmetry and the possible reasons for this structure are discussed." @default.
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- W252506597 date "1974-05-01" @default.
- W252506597 modified "2023-09-27" @default.
- W252506597 title "Spectra and structure of small ring compounds" @default.
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- W252506597 doi "https://doi.org/10.1016/0022-2860(74)80051-7" @default.
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