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- W2525136616 abstract "Response surface method is applied here to trace the photochromic path and explore the substituent and β-cyclodextrin effects on the decoloration of the spiropyran/β-cyclodextrin polymer (SP/CDP) complex. Calculations support the ultraviolet/visible experimental results, suggesting that introducing an electron-withdrawing group to the benzopyryl moiety of SPs favors an enhancement in their decoloration, whereas replacing the benzopyryl with a naphthopyryl moiety obstructs their decoloration. CDP complexation weakens the C1O bond of the closed SP form and enhances the polar zwitterionic structure in the open photomerocynine form. However, the electron-withdrawing group strengthens the interaction of benzopyryl SPs with CDP, thereby hindering their decoloration." @default.
- W2525136616 created "2016-10-07" @default.
- W2525136616 creator A5048168497 @default.
- W2525136616 date "2016-10-01" @default.
- W2525136616 modified "2023-09-30" @default.
- W2525136616 title "Application of response surface methodology for exploring β-cyclodextrin effects on the decoloration of spiropyran complexes" @default.
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- W2525136616 doi "https://doi.org/10.1016/j.cplett.2016.09.068" @default.
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