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• W2525192902 endingPage "4915" @default.
• W2525192902 startingPage "4912" @default.
• W2525192902 abstract "Photoinduced catalytic Michael-type radical addition was achieved via olefin insertion into a nonacidic C(sp3)-H bond, utilizing 2-chloroanthraquinone as a C-H bond-cleaving catalyst and 1,1-bis(phenylsulfonyl)ethylene as an olefinic substrate. The present radical protocol allows carbon chain extension stemming from nonacidic C-H bonds, which complements alkylation at acidic C-H bonds under ionic conditions and installs the active methine site that acts as a versatile synthetic handle for further transformations." @default.
• W2525192902 created "2016-10-07" @default.
• W2525192902 creator A5001539184 @default.
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• W2525192902 creator A5041921063 @default.
• W2525192902 creator A5066809881 @default.
• W2525192902 creator A5073348936 @default.
• W2525192902 date "2016-09-26" @default.
• W2525192902 modified "2023-10-06" @default.
• W2525192902 title "Alkylation of Nonacidic C(sp³)–H Bonds by Photoinduced Catalytic Michael-Type Radical Addition" @default.
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• W2525192902 doi "https://doi.org/10.1021/acs.orglett.6b02391" @default.
• W2525192902 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27668684" @default.
• W2525192902 hasPublicationYear "2016" @default.
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