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• W2525291292 abstract "Abstract The local structure of the rhombic Cu 2+ center in Cu 0.5 Zr 2 (PO 4 ) 3 phosphate is investigated by using the high-order perturbation formulas of electron paramagnetic resonance (EPR) parameters, g -factors g i ( i = x , y , z ), and hyperfine structure constants A i for 3d 9 ions in rhombically elongated octahedral symmetry. According to the studies, the local axial distortion angle Δ α (≈ 5.1°) and the planar bond angle θ (≈ 83.8°) in [CuO 6 ] 10- cluster was obtained. The theoretical EPR parameters based on the aforementioned local structure parameters show good agreement with the observed values, and some improvement have been made as compared with the previous studies." @default.
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• W2525291292 date "2015-07-01" @default.
• W2525291292 modified "2023-09-23" @default.
• W2525291292 title "Theoretical Studies of the Local Structures and EPR Parameters for the Rhombic Cu2+ Center in Cu0.5Zr2(PO4)3 Phosphate" @default.
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• W2525291292 doi "https://doi.org/10.1515/zna-2015-0128" @default.
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