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- W2525389384 abstract "A new rhodamine B derivative, namely, N1-(benzo[d]thiazol-2-yl)-N4-(2-(3′,6′-bis (diethylamino)-3-oxospiro[isoindoline-1,9′-xanthen]-2-yl)ethyl)malea-mide (RDBSF), was designed, synthesized, and structurally characterized to develop a new chemosensor. UV–vis absorption and fluorescence spectroscopic studies show that RDBSF exhibits high sensitivity and selectivity toward Fe3+ in the presence of many other metal cations in a Tris-HCl solution (1 mM, pH = 7.4) containing 30% MeCN by forming a 1:1 complex with Fe3+. The binding association constant (Ka) of RDBSF for Fe3+ was estimated as 1.52 × 104 M−1 in the solution. The detection limit of Fe3+ by RDBSF was further determined as 11.6 nM. Intracellular imaging applications demonstrated that RDBSF can be used as a fluorescent probe for the detection of Fe3+ in HepG-2 cells." @default.
- W2525389384 created "2016-10-07" @default.
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- W2525389384 date "2017-04-01" @default.
- W2525389384 modified "2023-10-03" @default.
- W2525389384 title "Synthesis and evaluation of a novel rhodamine B-based ‘off-on’ fluorescent chemosensor for the selective determination of Fe3+ ions" @default.
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- W2525389384 doi "https://doi.org/10.1016/j.snb.2016.09.163" @default.
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