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- W2525556803 abstract "A novel approach to PLA toughening is proposed in this study. Poly(lactic acid) (PLA) is toughened using poly(ethylene-n-butylene-acrylate-co-glycydyl methacrylate) (EBA-GMA) as a reactive compatibilizer with the aid of an epoxy-based chain extender. It is found that the toughening effect of EBA-GMA in the binary blend investigated is strongly influenced by blending temperature. Blending at high temperatures which are non-typical for PLA processing (over 250 °C) allows toughness to be increased by an order of magnitude when compared to the toughness of blends prepared at low temperatures (below 200 °C). This effect is attributed to a combination of factors, namely an increasing rate of reactive bonding between PLA and EBA-GMA at elevated temperatures and enhanced interfacial adhesion between PLA and EBA-GMA phases. DSC studies show that PLA/EBA-GMA bonding on the interface acts as an efficient nucleator for PLA. The nucleation ability of the PLA/EBA-GMA interface strongly depends on blend processing temperature and gradually increases with increasing blending temperature. The PLA/EBA-GMA interface shows its highest nucleation ability at 250 °C." @default.
- W2525556803 created "2016-10-07" @default.
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- W2525556803 date "2016-09-28" @default.
- W2525556803 modified "2023-10-16" @default.
- W2525556803 title "A New Approach to Supertough Poly(lactic acid): A High Temperature Reactive Blending" @default.
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- W2525556803 doi "https://doi.org/10.1002/mame.201600242" @default.
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