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• W2525983676 abstract "Three titanosilicate zeolites were used as fillers for Mixed Matrix Membranes: (i) ETS-10, (ii) TS-1 having Si/Ti=100 and (iii) TS-1 using Si/Ti=25. Zeolite samples were characterized by X-Ray Diffraction, Scanning Electron Microscopy, Atomic Emission Spectroscopy, X-Ray Photoelectron Spectroscopy, and CO2 and CH4 adsorption isotherms. TS-1 particles showed a narrow size distribution ranging from 200 nm to 400 nm. In the case of ETS-10, the size distribution was broader ranging from 400 nm to 800 nm. Mixed Matrix Membranes were prepared using Matrimid® polyimide as continuous phase and filler loadings of 10, 20, and 30 wt%. Membranes were characterized by Thermogravimetric Analysis, Differential Scanning Calorimetry, and Scanning Electron Microscopy. The performances was measured at 8 bars of transmembrane pressure for CO2/CH4 mixed gases system at 50/50 vol/vol. concentration. Membranes using TS-1 (Si/Ti=25) as filler showed a maximum increase of 89.1% of CO2 permeability and 23.9% increase in separation factor. In the case of TS-1 (Si/Ti=100) only permeability increased significantly, with a maximum increase of 90.1%. Regarding the ETS-10 membranes, both permeability and separation factor increased slightly with respect to the reference polymeric membrane (22.5% in CO2 permeability and 7.8% in the separation factor). In conclusion, TS-1 (Si/Ti=25) is the most suitable filler for the use in Mixed Matrix Membranes for gas separation applications among the titanosilicate studied in this work." @default.
• W2525983676 created "2016-10-07" @default.
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• W2525983676 date "2017-02-01" @default.
• W2525983676 modified "2023-10-01" @default.
• W2525983676 title "Study of different titanosilicate (TS-1 and ETS-10) as fillers for Mixed Matrix Membranes for CO2/CH4 gas separation applications" @default.
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• W2525983676 doi "https://doi.org/10.1016/j.memsci.2016.09.041" @default.
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