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• W2526131062 startingPage "2183" @default.
• W2526131062 abstract "The microwave spectrum of trans-crotonaldehyde has been measured in the frequency region from 8.2 to 36 kMc/sec. The R-branches for the a-type and the R- and Q-branches for the b-type have been assigned. The low J transitions of the a-type and all of the b-type transitions are split into the A-level and the E-level by the internal rotation of the methyl group. The apparent rotational constants for the A- and E-levels have been obtained from the pseudo-rigid rotor approximation as AA=32636.58 Mc/sec, AE=32627.57 Mc/sec, B=2183.30 Mc/sec, and C=2073.32 Mc/sec. From these values it can be concluded that this molecule is of the s-trans form. The barrier height of the hindering rotation of the methyl group is 1730±10 cal/mol. The value of the total dipole moment is 3.72±0.28 D." @default.
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• W2526131062 date "1969-08-01" @default.
• W2526131062 modified "2023-10-10" @default.
• W2526131062 title "Microwave Spectrum, Barrier to Internal Rotation, and Dipole Moment of<i>trans</i>-Crotonaldehyde" @default.
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• W2526131062 doi "https://doi.org/10.1246/bcsj.42.2183" @default.
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