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- W2526276626 startingPage "1617" @default.
- W2526276626 abstract "Elementary processes in the radiolysis of ethyl mercaptan has been investigated by both spectrophotometric and electron spin resonance (ESR) methods. Ethyl mercaptan (C2H5SH) forms a glassy solid at 77°K, and when irradiated with γ-rays from Co-60, it develops a deep orange color; this color fades upon illumination with visible light, leaving a clear yellow color. The ESR spectrum of γ-irradiated C2H5SH at 77°K consists of two components; one is a complex spectrum which has been identified with the spectrum of C2H5S·, while the other is a photobleachable broad singlet which has been assigned to the ionic species. The C2H5S· radical shows an absorption spectrum with λmax=405 nm. The G-values for the formation of the radicals and the ionic species were 0.5 and 2.9 respectively. Studies of 2-methyltetrahydrofuran and butyl chloride solutions of C2H5SH were performed to identify these ionic species. Some significant elementary processes will be discussed on the basis of these results." @default.
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- W2526276626 date "1970-06-01" @default.
- W2526276626 modified "2023-10-17" @default.
- W2526276626 title "Reaction Intermediates in γ-Irradiated Mercaptans at 77°K" @default.
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- W2526276626 doi "https://doi.org/10.1246/bcsj.43.1617" @default.
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