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• W2527188648 abstract "ABSTRACTNovel pH-sensitive amphiphilic comb-shaped copolymers containing long fluorinated side chains, which combined the characteristics of pH-sensitivity from pendent tertiary amine groups, unique hydrophobic and fluorophobic characteristic from the fluorinated moieties and hydrophilicity from the poly (ethylene glycol) segments, were designed and synthesized via radical polymerizaion of 2-(Dimethylamino) ethyl methacrylate (DMAEMA), poly (ethylene glycol) methyl ether methacrylate (PEGMA) and homemade fluorinated macromonomer (PHFBMA-GMA). The physicochemical properties of polymeric micelles prepared therefrom were investigated. The chemical structures of the copolymers were characterized by GPC, FTIR and 1H-NMR. The critical micelle concentrations (CMC) of the copolymers in different pH (5.0 and 7.4) were determined by fluorescence spectroscopy. Larger CMCs could be obtained in lower pH since the pronation of DMAEMA moieties enhanced the hydrophilicity. With increasing the amount, as well as the molec..." @default.
• W2527188648 created "2016-10-07" @default.
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• W2527188648 date "2016-09-29" @default.
• W2527188648 modified "2023-09-26" @default.
• W2527188648 title "Preparation and self-assembly of pH-sensitive amphiphilic comb-shaped copolymer containing long fluorinated side chains" @default.
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• W2527188648 doi "https://doi.org/10.1080/10601325.2016.1224630" @default.
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