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- W2527768075 abstract "A novel method for intermolecular functionalization of terminal and internal alkenes has been designed. The electrophilic reagent, hypervalent iodine, plays a key role in this process by activating the alkene C=C bond for nucleophilic addition of the palladium catalyst. This process generates an iodonium-containing palladium species which undergoes CO insertion. The new approach, intermolecular oxycarbonylaton reactions of alkenes, has been achieved and carried out under mild reaction conditions to produce the corresponding β-oxycarbonylic acids with excellent efficiencies and levels of regio- and diastereoselectivity." @default.
- W2527768075 created "2016-10-14" @default.
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- W2527768075 date "2016-10-06" @default.
- W2527768075 modified "2023-10-13" @default.
- W2527768075 title "A Cooperative Strategy for the Highly Selective Intermolecular Oxycarbonylation Reaction of Alkenes using a Palladium Catalyst" @default.
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- W2527768075 doi "https://doi.org/10.1002/anie.201607248" @default.
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