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• W2527768105 abstract "The title complex, [CuCl(C20H18N4O4)(C18H15P)], has two mol­ecules in the asymmetric unit. The Cu atom is four-coordinate in a distorted tetra­hedral geometry, bonded to two imine N atoms of the Schiff base, Cl and PPh3; the main distortion is the small bite angle of the chelating Schiff base ligand. One triphenyl­phospine ligand adopts an approximate propeller conformation, with dihedral angles of 69.36 (14), 77.02 (12) and 82.44 (15)° for pairs of benzene rings, the normals of which make angles of 37.8, 65.4 and 72.6° with the P—Cu bond; the arrangement in the other triphenyl­phosphine ligand is rather less symmetrical, with dihedral angles of 63.41 (15), 70.67 (12) and 78.11 (12)° and angles of 20.3, 78.6 and 83.2° between the ring plane normals and the P—Cu bond. There are inter­molecular C—H⋯Cl and C—H⋯O inter­actions. The crystal was a non-merohedral twin, with approximately equal contributions of the two domains." @default.
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• W2527768105 date "2007-11-09" @default.
• W2527768105 modified "2023-10-14" @default.
• W2527768105 title "{<i>N</i>,<i>N</i>′-Bis[3-(2-nitrophenyl)prop-2-enylidene]ethylenediamine-κ²<i>N</i>,<i>N</i>′}chlorido(triphenylphosphine-κ<i>P</i>)copper(I)" @default.
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• W2527768105 doi "https://doi.org/10.1107/s1600536807056267" @default.
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